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Synthesis, structural characterization and alcohol oxidation activity of a new mononuclear manganese(II) complex

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Abstract

A manganese(II) complex of 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz) has been synthesized and characterized by single-crystal X-ray diffraction, elemental analyses, IR, and UV–Vis spectroscopic techniques. Oxidation of alcohols to their corresponding aldehydes and ketones was conducted by this catalyst using oxone (2KHSO5·KHSO4·K2SO4) as an oxidant under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent under air at room temperature. Easy preparation, mild reaction conditions, high yields of the products, short reaction times, no further oxidation to the corresponding carboxylic acids, high selectivity and inexpensive reagents make this catalytic system a useful oxidation method for aliphatic and benzylic alcohols.

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Acknowledgements

We are grateful to the Research Council of Sharif University of Technology and National Elite Foundation for their financial support.

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Authors and Affiliations

  1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences, 45195-1159, Gava Zang, Zanjan, Iran

    Mohammad Mahdi Najafpour

  2. Chemistry Department, Sharif University of Technology, PO Box 11155-3516, Tehran, Iran

    Mojtaba Amini, Mojtaba Bagherzadeh & Davar M. Boghaei

  3. Department of Chemistry, Loughborough University, Leicestershire, LE11 3TU, UK

    Vickie McKee

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  1. Mohammad Mahdi Najafpour
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  2. Mojtaba Amini
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  3. Mojtaba Bagherzadeh
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  4. Davar M. Boghaei
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  5. Vickie McKee
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Corresponding author

Correspondence to Davar M. Boghaei.

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Najafpour, M.M., Amini, M., Bagherzadeh, M. et al. Synthesis, structural characterization and alcohol oxidation activity of a new mononuclear manganese(II) complex. Transition Met Chem 35, 297–303 (2010). https://doi.org/10.1007/s11243-010-9327-4

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